The effect was at first observed by Arthur Holly Compton in 1923 at Washington University in St. Louis and explained in his article "A Quantum Theory of the Scattering of X-ray by Light Elements". Compton was rewarded the 1927 Nobel Prize in Physics for this discovery.. He used the Planck relationship and the relativistic energy expression to derive the standard Compton formula:
Here, Δλ denotes the difference between the wavelengths of the incoming and the scattered ray, while θ is the angle of scattering.
The Compton Experiment
A collimated beam of high-energy photons, e.g. emitted from a radioactive 137Cs source or an X-ray emitter hits a target, e.g. a rod of graphite. A scintillation counter is used to measure the number and the energy of the deflected photons at various angles.
The number of photons should vary with the angle of the deflection, while the energy (i.e., the wavelength) of the photons should remain unchanged.
While indeed many of the scattered photons have an unchanged wavelength, there are some which lost energy, i.e., their wavelength lengthened. This lengthening depends on the angle of the deflection only.
The lengthening of the wave-length happens when a photon interacts with a free electron in the material. The effect can be calculated along the following lines.
1) Conservation of energy: We assume that before the collision, the electron is nearly at rest, so its kinetic energy is zero: Ee = 0. The photon has an energy of Eγ = hf, where h is Planck's constant, and f is its initial frequency. After the interaction, the photon's frequency changed to f', so its energy is now E'γ = hf'. The kinetic energy of the electron after the collision is . (Here, me is the mass of the electron.) We get the equation;
(here, is the momentum of the electron after the event)
2) Conversation of momentum: As we assume that the electron is nearly at rest at first, its initial momentum is zero. The momentum of the photon is at first and then . The momentum of a photon can be calculated via p = E / c = hf / c.
Looking at the picture, we see that
p2 + p'2 − 2pp'cosθ, thus
I: (pec)2 = (hf)2 + (hf')2 − 2h2ff'cosθ
Squaring and rearranging leads to:
II: (pec)2 = (hf)2 + (hf')2 − 2h2ff' + 2mec2(hf − hf')
We equate our I and II and get:
− 2h2ff'cosθ = − 2h2ff' + 2mec2(hf − hf')
This we rearrange to:
As for a photon fλ = c, we can bring this into Compton's form:
This describes exactly the effect observed by Compton! Compton himself used a similar derivation, also including the relativistic energy expression.
Probability of Compton Scattering
The probability for Compton scattering is approximately proportional to the atomic number Z, and for energies greater than 500 keV approximately proportional to , the energy of the gamma ray photon.