A fundamental principle of quantum mechanics is that there is an uncertainty in the location of a subatomic particle until it is observed. This insight is essential for understanding certain concepts that classical physics cannot explain, such as the discrete nature of small-scale interactions, wave-particle duality, the uncertainty principle, and quantum entanglement. Quantum mechanics forms the basis for our understanding of many phenomena, including chemical reactions and radioactive decay, and is used by all computers and electronic devices today. In addition, quantum mechanics explains why the Second Law of Thermodynamics is always true. Quantum mechanics may also help explain the foundation of the aging process that affects all life.
The order created by God is on a foundation of uncertainty. The Book of Genesis explains that the world was an abyss of chaos at the moment of creation. Quantum mechanics is predicted in several additional respects by the Biblical scientific foreknowledge.
The term "quantum mechanics" comes from the idea that energy is transmitted in discrete quanta, and not continuous. Another historical name for "quantum mechanics" was "wave mechanics."
Until the early 1900s, scientists believed that electrons and protons were small discrete lumps. Thus, electrons would orbit the nucleus of an atom just as planets orbit the sun. The problem with this idea was that, according to classical electromagnetism, the orbiting electron would emit energy as it orbited. This would cause it to lose rotational kinetic energy and orbit closer and closer to the proton, until it collapses into the proton! Since atoms are stable, this model could not be correct.
The idea of "quanta", or discrete units, of energy was proposed by Max Planck in 1900, to explain the energy spectrum of black body radiation. He proposed that the energy of what we now call a photon is proportional to its frequency. In 1905, Albert Einstein also suggested that light is composed of discrete packets (quanta) in order to explain the photoelectric effect.
In 1915, Niels Bohr applied this to the electron problem by proposing that angular momentum is also quantized - electrons can only orbit at certain locations, so they cannot spiral into the nucleus. While this model explained how atoms do not collapse, not even Bohr himself had any idea why. As Sir James Jeans remarked, the only justification for Bohr's theory was "the very weighty one of success".
It was Prince Louis de Broglie who explained Bohr's theory in 1924 by describing the electron as a wave with wavelength λ=h/p. Therefore, it would be logical that it could only orbit in orbits whose circumference is equal to an integer number of wavelengths. Thus, angular momentum is quantized as Bohr predicted, and atoms do not self-destruct.
Eventually, the mathematical formalism that became known as quantum mechanics was developed in the 1920s and 1930s by John von Neumann, Hermann Weyl, and others, after Erwin Schrodinger's discovery of wave mechanics and Werner Heisenberg's discovery of matrix mechanics.
The work of Tomonaga, Schwinger and Feynman in quantum electrodynamics led to the modern framework of quantum mechanics, currently applicable in quantum electrodynamics and quantum chromodynamics.
- Every system can be described by a wave function, which is generally a function of the position coordinates and time. All possible predictions of the physical properties of the system can be obtained from the wave function. The wave function can be obtained by solving the Schrodinger equation (or the Klein-Gordon equation for relativistic-quantum mechanics) for the system.
- An observable is a property of the system which can be measured. In some systems, many observables can take only certain specific values.
- If we measure such an observable, generally the wave function does not predict exactly which value we will obtain. Instead, the wave function gives us the probability that a certain value will be obtained. After a measurement is made, the wave function is permanently changed in such a way that any successive measurement will certainly return the same value. This is called the collapse of the wave function.
Collapse of The Wave Function
In quantum mechanics, it is meaningless to make absolute statements such as "the particle is here". This is a consequence of the Heisenberg Uncertainty Principle which (simply put) states, "particles move," in an apparently random manner. Thus, giving a definite position to a particle is meaningless. Instead, scientists use the particle's "position function," or "wave function," which gives the probability of a particle being at any point. As the function increases, the probability of finding the particle in that location increases. In the diagram, where the particle is free to move in 1 direction, we see that there is a region (close to the y-axis) where the particle is more likely to be found. However, we also notice that the wave function does not reach zero as it moves towards infinity in both directions. This means that there is a high likelihood of finding the particle around the center, but there is still a possibility that, if measured, the particle will be a long ways away.
When the particle is actually observed to be in a specific location, its wave function is said to have "collapsed". This means that if it is again observed immediately the probability that it will be found near the original location is almost 1. However, if it is not immediately observed, the wave function reverts to its original shape as expected. The collapsed wave function has a much narrower and sharper peak than the original wave function.
Collapsing of the wave function is by no means magic. In can be intuitively understood as this: You find a particle at a particular spot; if you look again immediately, it's still in the same spot.
The uncertainty principle
As a result of the wave nature of a particle, certain quantities cannot be known to an arbitrary precision simultaneously. This happens when the operators for the two quantities do not commute. An example is position and momentum. Whenever its position is measured more accurately (beyond a certain limit), its momentum becomes less certain, and vice versa. Hence, there is an inherent uncertainty that prevents precisely measuring both the position and the momentum simultaneously. This is known as the Heisenberg Uncertainty Principle:
- is the standard deviation (uncertainty) of position
- is the standard deviation of momentum
- is the reduced Planck's constant
Other examples include energy and time, as well as different components of angular momentum.
The probability a particle is found in a certain region can be described as:
provided that the wave function is normalised:
In general, the expected value of a measurement of a quantity can be described as:
so that the expected momentum is:
Several interpretations have been advanced to explain how wavefunctions "collapse" to yield the observable world we see.
- The "hidden variable" interpretation says that there is actually a deterministic way to predict where the wave function will collapse; we simply have not discovered it. John von Neumann attempted to prove that there is no such way; however, John Stuart Bell pointed out an error in his proof.
- The many-worlds interpretation says that each particle does show up at every possible location on its wave function; it simply does so in alternate universes. Thus, myriads of alternate universes are invisibly branching off of our universe every moment.
- The currently prevailing interpretation, the Copenhagen interpretation, states that the wave functions do not collapse until the particle is observed at a certain location; until it is observed, it exists in a quantum indeterminate state of simultaneously being everywhere in the universe. However, Schrodinger, with his famous thought experiment, raised the obvious question: who, or what, constitutes an observer? What distinguishes an observer from the system being observed? This distinction is highly complex, requiring the use of quantum decoherence theory, parts of which are not entirely agreed upon. In particular, quantum decoherence theory posits the possibility of "weak measurements", which can indirectly provide "weak" information about a particle without collapsing it.
An important aspect of Quantum Mechanics is the predictions it makes about the radioactive decay of isotopes. Radioactive decay processes, controlled by the wave equations, are random events. A radioactive atom has a certain probability of decaying per unit time. As a result, the decay results in an exponential decrease in the amount of isotope remaining in a given sample as a function of time. The characteristic time required for 1/2 of the original amount of isotope to decay is known as the "half-life" and can vary from quadrillionths of a second to quintillions of years.
Quantum Mechanics has important applications in chemistry. The field of Theoretical Chemistry consists of using quantum mechanics to calculate atomic and molecular orbitals occupied by electrons. Quantum Mechanics also explain different spectroscopy used everyday to identify the composition of materials.
Concepts in quantum mechanics
Important contributors to quantum mechanics
- The quantum in QM is Planck's constant. Its units are angular (or rotational) momentum. If the value of this constant were much larger, then a human being might be able to perceive the impact of the constant by pulling the string to spin up a very rigid toy gyroscope. They would feel tugs at the gyro acquired more units of the constant. They could then set the gyro down in its frame and watch the rate of spin reduce due to friction in steps, rather than smoothly, and then finally abruptly snap down to a resting state. There are many non-intuitive implications of such a quantization. Perhaps the most immediate implication of the constant is the discrete nature of the first electron orbital of the hydrogen atom. As one proceeds to higher orbitals, non-intuitive non-spherical three-dimensional harmonic patterns emerge and these dominate in the next-higher-level structure of matter. An important example for humans is p-orbitals of the carbon atom that implement the carbon chains of the macro-molecules that implement all known forms of life. There are many other non-intuitive implications of QM. QM has gone through several distinct mathematical formulations. The implications of QM that are well-understood are considered by most scientists to be laws of nature.
For an excellent discussion of quantum mechanics, see: