Ethanol

2007-05-13T00:05:47Z

MARK4PROPANE: /* Controversy */

'''Ethanol''', also known as [[grain alcohol]] is a flammable [[chemical compound]] with a strong [[odor]], and is the primary [[alcohol]] found in [[alcoholic beverage]]s. In common usage, it is often referred to simply as alcohol. The chemical formula is variously represented as EtOH, CH3CH2OH, C2H5OH.

Ethanol is also a [[biofuel]] made from [[alcohol]] and is an [[oxygenate]] that is added to [[gasoline]] to increase the [[octane]] rating. The product is produced through the [[fermentation]] of [[corn]], or other cellulosic material.

==Process==

Ethanol for use in [[alcoholic beverage]]s, and the vast majority of ethanol for use as fuel, is produced by fermentation: when certain species of [[yeast]] (most importantly, ''[[Saccharomyces cerevisiae]]'') [[metabolism|metabolize]] [[saccharide|sugar]] in the absence of [[oxygen]], they produce ethanol and [[carbon dioxide]]. The overall chemical reaction conducted by the yeast may be represented by the chemical equation

: [[glucose|C6H12O6]] → 2 CH3CH2OH + 2 [[carbon dioxide|CO2]]

The process of culturing yeast under conditions to produce alcohol is referred to as [[brewing]]. Brewing can only produce relatively dilute concentrations of ethanol in water; concentrated ethanol solutions are [[toxicity|toxic]] to yeast. The most ethanol-tolerant strains of yeast can survive in up to about 15% ethanol by volume.

During the fermentation process, it is important to prevent oxygen from getting to the ethanol, since otherwise the ethanol would be oxidised to [[acetic acid]] (vinegar). Also, in the presence of oxygen, the yeast would undergo [[aerobic respiration]] to produce just [[carbon dioxide]] and water, without producing ethanol.

In order to produce ethanol from starchy materials such as [[cereal grain]]s, the starch must first be broken down into sugars. In brewing [[beer]], this has traditionally been accomplished allowing the grain to germinate, or [[malt]]. In the process of germination, the seed produces [[enzyme]]s that can break its starches into sugars.

==Co-products==

A co-product of the fermentation process is [[distillers grains]] which can be used as cattle feed. Distillers grains is termed either [[wet distillers grains]] or [[dried distillers grains]] or simply [[DDGs]]. Wet distillers grains have a very short shelf life as they are susceptible to microorganisms that can pollute the material and render it unfit for cattle consumption.

==Ethanol Industry==

In the [[United States]] ethanol is most commonly made through the fermentation of corn. Other countries, such as [[Brazil]] use sugar as a [[catalyst]] for the fermenting process. Currently, the US has the highest production numbers for ethanol in the world, but some analysts forecast China as being a potential world player in the ethanol market. [[China]] currently uses [[casava]] and [[wheat]] among other material for producing ethanol.

==Controversy==

Some in the [[Food vs. Fuel]] debate consider the use of a high-energy food crop, such as corn, detrimental to our food supply. In particular, [[Lester Brown]] of the [[Earth Policy Institute]] is known for advocating this position.

[[Category:Chemistry]]The latest automotive grade of ethanol in Canada has 1% water. This is specified by the CSB, the Canadian Standards Board. Water is terrible for any fuel injection system and will probably lead to corrosion of the fuel injectors and fuel pumps.

The auto fuel ethanol government standards in Brazil, do not allow any water.

One major gasoline wholesaler and retailer in Canada has used 8% ethanol in all it's grades of gasoline for over 10 years because it was one of the cheapest ways to boost the octane rating of gasoline. The R+M rating of ethanol is 104.

Etnanol has about 36% oxygen by weight whereas normal gasoline has no oxygen.
This is why a car runs much smoother at very low temperatures during the first 2 or 3 minutes as the oxygen content in ethanol enhanced gasoline allows a hotter, cleaner burn. --[[User:MARK4PROPANE|MARK4PROPANE]] 20:05, 12 May 2007 (EDT)

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Ethanol