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==History==
 
==History==
About 120 A.D. Heron of Alexandria created the first reaction turbine, essentially a copper sphere with two bent nozzles mounted opposite each other; the sphere itself was mounted above a fire which heated water within the sphere, causing the sphere to rapidly rotate via the steam escaping from the nozzles.  Simply a curious novelty at the time, Heron's sphere would cause speculation on the nature of heat and heat transfer, and spark some investigation into using heat transfer to accomplish meaningful work.
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It has been known since antiquity that, when hot and cold objects are juxtaposed to each other, the warmer one cools off while the cooler one warms up, until they reach the same temperature.  That is, heat only flows "downhill", never "uphill".  It would take much scientific inquiry to figure out why this is so.
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This didn't stop people from constructing heat engines.  About 120 A.D. Heron of Alexandria created the first reaction turbine, essentially a copper sphere with two bent nozzles mounted opposite each other; the sphere itself was mounted above a fire which heated water within the sphere, causing the sphere to rapidly rotate via the steam escaping from the nozzles.  Simply a curious novelty at the time, Heron's sphere would cause speculation on the nature of heat and heat transfer, and spark some investigation into using heat transfer to accomplish meaningful work.
    
In 1789 Antoine Lavoisier demonstrated the law of conversion of mass, when he observed that heat flowed from a warm body to a cold one.  He proposed that heat was an element (he called this element ''caloric''), and speculated that it was a type of fluid surrounding an atom, and seemingly confirmed his theory when he removed oxygen from mercuric oxide.   
 
In 1789 Antoine Lavoisier demonstrated the law of conversion of mass, when he observed that heat flowed from a warm body to a cold one.  He proposed that heat was an element (he called this element ''caloric''), and speculated that it was a type of fluid surrounding an atom, and seemingly confirmed his theory when he removed oxygen from mercuric oxide.   
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The downfall of Lavoisier's caloric theory happened at the arsenal in Munich, Germany.  The Bavarian minister of war was a British expatriate, Sir Benjamin Thompson, and he observed that work was being converted into heat by observing the boring of a cannon.  If caloric theory was correct, he reasoned, no more heat would be made once all of the caloric was removed from the cannon at the atomic level, yet his observations on this procedure - including a cannon bored while under water - demonstrated that work can be converted into heat, like the steam engines of his time converting heat into work.   
 
The downfall of Lavoisier's caloric theory happened at the arsenal in Munich, Germany.  The Bavarian minister of war was a British expatriate, Sir Benjamin Thompson, and he observed that work was being converted into heat by observing the boring of a cannon.  If caloric theory was correct, he reasoned, no more heat would be made once all of the caloric was removed from the cannon at the atomic level, yet his observations on this procedure - including a cannon bored while under water - demonstrated that work can be converted into heat, like the steam engines of his time converting heat into work.   
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James Joule in 1849 made a precise determination of the mechanical equivalent of heat into work.  His stirring of water in a pot (work input with a mechanical stirring rod, caused by the motion of a 1-kg weight falling 42.4 cm) caused a temperature increase (heat output); his homemade, yet very-precise thermometers recorded a conversion factor of 0.241 calories of heat energy (now called ''one joule'').
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James Joule in 1849 made a precise determination of the mechanical equivalent of heat into work.  His stirring of water in a pot (work input with a mechanical stirring rod, caused by the motion of a 1-kg weight falling 42.4 cm) caused a temperature increase (heat output); his homemade, yet very-precise thermometers recorded the conversion factor. The unit of energy is now called the ''[[International_System_of_Units#Joule|joule]]''.  4.2 joules of energy can raise one gram of water 1 degree Celsius, an amount called one calorie.  (The large-C "Calorie" used in nutritional measure is 1000 small-c calories.)
    
==[[First Law of Thermodynamics]]==
 
==[[First Law of Thermodynamics]]==
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