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| | If a electron in the ground state absorbed energy it would be able to be promoted to a higher energy orbit. After time it would fall back to its original state releasing a photon of light with energy corresponding to the gap between the two levels. The electron did not necessarily fall straight back, for example it could jump from n=1 to n=3 and either fall back from n=3 to n=1 or from n=3 to n=2 and then n=2 to n=1. As the energy levels between each level were different this allowed for a number of wavelengths to be emitted if a sample was exposed to a large energy source, however as the values were fixed only specific wavelengths were allowed hence explaining the discrete lines on the emission spectra of elements. | | If a electron in the ground state absorbed energy it would be able to be promoted to a higher energy orbit. After time it would fall back to its original state releasing a photon of light with energy corresponding to the gap between the two levels. The electron did not necessarily fall straight back, for example it could jump from n=1 to n=3 and either fall back from n=3 to n=1 or from n=3 to n=2 and then n=2 to n=1. As the energy levels between each level were different this allowed for a number of wavelengths to be emitted if a sample was exposed to a large energy source, however as the values were fixed only specific wavelengths were allowed hence explaining the discrete lines on the emission spectra of elements. |
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| − | Bohr modeled his atom on the emission spectrum of hydrogen. The [[Element|elemental]] atom of hydrogen at ground state contains an electron in the first electron orbit, n=1. When the atom is excited the electron can jump into a higher state including energy levels n=2, n=3, n=4, n=5, n=6, and then would fall back to its ground state. Bohr calculated a number of transitions were possible, including: | + | Bohr modeled his atom on the emission spectrum of hydrogen. The [[element]]al atom of hydrogen at ground state contains an electron in the first electron orbit, n=1. When the atom is excited the electron can jump into a higher state including energy levels n=2, n=3, n=4, n=5, n=6, and then would fall back to its ground state. Bohr calculated a number of transitions were possible, including: |
| − | * Paschen Series - wavelength in the [[Infra red|IR]] range, when an electron falls to n=3 from a higher orbit | + | * Paschen Series - wavelength in the [[Infrared|IR]] range, when an electron falls to n=3 from a higher orbit |
| | * Balmer Series - wavelength in the visible range, when an electron falls to n=2 from a higher orbit, specifically | | * Balmer Series - wavelength in the visible range, when an electron falls to n=2 from a higher orbit, specifically |
| | ** n=3 to n=2 - 656.3nm (red) | | ** n=3 to n=2 - 656.3nm (red) |
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| | ** n=7 to n=2 - 397.0nm (violet) | | ** n=7 to n=2 - 397.0nm (violet) |
| | ** n=8 to n=2 - 388.9nm (violet) | | ** n=8 to n=2 - 388.9nm (violet) |
| − | * Lymann Series - wavelength in the [[Ultra violet|UV]] range, when an electron falls from n=2 to n=1 | + | * Lymann Series - wavelength in the [[Ultraviolet|UV]] range, when an electron falls from n=2 to n=1 |
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| | ==Limitations== | | ==Limitations== |