First Law of Thermodynamics

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The First Law of Thermodynamics is that the increase in internal energy of a closed system equals the amount of heat energy added minus the work performed by the system.

Mathematically, this is described as follows:

where is the infinitesimal increase in the internal energy, is the infinitesimal amount of heat added, and is the infinitesimal amount of work performed.

Note that if no energy is added, then the maximum amount of work that can be performed by the system is equal to its initial energy. This prevents the existence of a type of perpetual motion machine.