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Hundreds of years of research by chemists (and, before that, the alchemists) worked out the potential energies that are characteristic of various substances, and that the potential and kinetic energies are accurately converted from one to the other, leading to the principle of conservation of total energy.
 
Hundreds of years of research by chemists (and, before that, the alchemists) worked out the potential energies that are characteristic of various substances, and that the potential and kinetic energies are accurately converted from one to the other, leading to the principle of conservation of total energy.
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An interesting fact is that, normally, one considers only ''changes'' in potential energy; one doesn't need an absolute scale.  A rock at the top of a hill has more potential energy than after it rolls to the bottom of the hill, but the energy at the bottom isn't necessarily zero.  We could dig a hole and let it roll down farther, with its energy going negative.  Only changes matter.  Now it turns out that, once one accepts the implications of E=mc², one ''could'' assign an absolute potential energy to something—its mass times c², and changes in potential emergy would work out correctly because of the mass changes.  But that isn't necessary, and, in any case, it would require accepting E=mc² and would therefore be getting ahead of the story.
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An interesting fact is that, normally, one considers only ''changes'' in potential energy; one doesn't need an absolute scale.  A rock at the top of a hill has more potential energy than after it rolls to the bottom of the hill, but the energy at the bottom isn't necessarily zero.  We could dig a hole and let it roll down farther, with its energy going negative.  Only changes matter.  Now it turns out that, once one accepts the implications of E=mc², one ''could'' assign an absolute potential energy to something—its mass times c², and changes in potential energy would work out correctly because of the mass changes.  But that isn't necessary, and, in any case, it would require accepting E=mc² and would therefore be getting ahead of the story.
     
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