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In 1960, Volentine graduated as the class president at Athens High School in Athens, Louisiana, in the building now occupied by Mt. Olive Christian School.<ref>Mt. Olive Christian School, former Athens High School class photographs by year.</ref> He then attended [[Louisiana Tech University]] in [[Ruston, Louisiana|Ruston]].<ref name=whoswho>"Louisiana: Kenneth Volentine," ''Who's Who in American Politics, 2007-2008'' (Marquis Who's Who: New Providence, [[New Jersey]], 2007), p. 674.</ref>  

In 1960, Volentine graduated as the class president at Athens High School in Athens, Louisiana, in the building now occupied by Mt. Olive Christian School.<ref>Mt. Olive Christian School, former Athens High School class photographs by year.</ref> He then attended [[Louisiana Tech University]] in [[Ruston, Louisiana|Ruston]].<ref name=whoswho>"Louisiana: Kenneth Volentine," ''Who's Who in American Politics, 2007-2008'' (Marquis Who's Who: New Providence, [[New Jersey]], 2007), p. 674.</ref>  

Volentine is member of the Athens Masonic Lodge  and one of seven members of the Claiborne Industrial Development Board.<ref>{{cite web|url=http://www.claiborneone.org/cedb1.html|title=Claiborne Industrial Development Board|publisher=claiborne.one.org|accessdate=January 2, 2011}}</ref>He is also affiliated with the Louisiana Cattleman's and Dairyman's associations. He is a [[Southern Baptist]].<ref name=whoswho/>

Volentine is member of the Athens Masonic Lodge  and one of seven members of the Claiborne Industrial Development Board.<ref>{{cite web|url=http://www.claiborneone.org/cedb1.html|title=Claiborne Industrial Development Board|publisher=claiborne.one.org|accessdate=January 2, 201; information no longer on-line}}</ref>He is also affiliated with the Louisiana Cattleman's and Dairyman's associations. He is a [[Southern Baptist]].<ref name=whoswho/>

Volentine and his wife, the former Beverly Ann Pixley (born 1940), reside in Athens, a rural community in southern Claiborne Parish. They have three children, Sherry Volentine Broughten, Angie Volentine Grayson, and Kenneth Volentine Jr., of Athens. Volentine also has two brothers, Edwin "Bo" Volentine (born 1942) and Dan Volentine, both of Athens, and a sister, Wanda V. Head (1943-2016) of [[Shreveport]].<ref name=fvobit/>​

Volentine and his wife, the former Beverly Ann Pixley (born 1940), reside in Athens, a rural community in southern Claiborne Parish. They have three children, Sherry Volentine Broughten, Angie Volentine Grayson, and Kenneth Volentine Jr., of Athens. Volentine also has two brothers, Edwin "Bo" Volentine (born 1942) and Dan Volentine, both of Athens, and a sister, Wanda V. Head (1943-2016) of [[Shreveport]].<ref name=fvobit/>​