The active monomer activates another unit (eg by causing its double bond to split), as there are now four free electrons a covalent bond can form between the two units and two electrons (one on each atom) will be left to combine with other units. This process continues and the chain grows in size with every unit added. During propagation side branching can occur, in which monomers start a secondary chain leading off the first. These chains can affect the properties of the end polymer, and can be controlled depending on the conditions in which polymerization occurs. | The active monomer activates another unit (eg by causing its double bond to split), as there are now four free electrons a covalent bond can form between the two units and two electrons (one on each atom) will be left to combine with other units. This process continues and the chain grows in size with every unit added. During propagation side branching can occur, in which monomers start a secondary chain leading off the first. These chains can affect the properties of the end polymer, and can be controlled depending on the conditions in which polymerization occurs. |